Hossain, G. M. Golzar and Amoroso, Angelo James  ORCID: https://orcid.org/0000-0002-7601-5482
2014.
Bis[4-amino-N-(4-methylpyrimidin-2-yl-[kappa]N3)benzenesulfonamidato-[kappa]N](2,2'-bipyridine-[kappa]2N,N')mercury(II).
Acta Crystallographica Section E - Structure Reports Online
70
(4)
, m127-m128.
10.1107/S1600536814004760
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Official URL: http://dx.doi.org/10.1107/S1600536814004760
Abstract
The complete molecule of the title complex, [Hg(C11H11N4O2S)2(C10H8N2)], is generated by crystallographic twofold symmetry, with the mercury cation lying on the rotation axis. The mercury coordination polyhedron can be described as tetrahedral (from the N,N'-bidenate bipyridine molecule and the sulfonamide N atoms of the sulfamerazine anions) or as squashed trigonal-prismatic, if two long (> 2.80 Å) Hg-N bonds to pyrimidine N atoms are included. The dihedral angle between the aromatic rings in the anion is 73.3 (2)°. In the crystal, N-H...(N,O) and N-H...N hydrogen bonds link the molecules into a three-dimensional network.
| Item Type: | Article |
|---|---|
| Date Type: | Published Online |
| Status: | Published |
| Schools: | Schools > Chemistry |
| Subjects: | Q Science > QD Chemistry |
| Publisher: | International Union of Crystallography |
| ISSN: | 1600-5368 |
| Date of First Compliant Deposit: | 28 April 2016 |
| Date of Acceptance: | 2 March 2014 |
| Last Modified: | 04 May 2023 23:59 |
| URI: | https://orca.cardiff.ac.uk/id/eprint/90067 |
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