Slocombe, Daniel Rhys ORCID: https://orcid.org/0000-0003-3590-6075, Kuznetsov, V. L., Grochala, W., Williams, R. J. P. and Edwards, P. P.
2015.
Superconductivity in transition metals.
Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences
373
(2037)
, 20140476.
10.1098/rsta.2014.0476
|
Abstract
A qualitative account of the occurrence and magnitude of superconductivity in the transition metals is presented, with a primary emphasis on elements of the first row. Correlations of the important parameters of the Bardeen–Cooper–Schrieffer theory of superconductivity are highlighted with respect to the number of d-shell electrons per atom of the transition elements. The relation between the systematics of superconductivity in the transition metals and the periodic table high-lights the importance of short-range or chemical bonding on the remarkable natural phenomenon of superconductivity in the chemical elements. A relationship between superconductivity and lattice instability appears naturally as a balance and competition between localized covalent bonding and so-called broken covalency, which favours d-electron delocalization and superconductivity. In this manner, the systematics of superconductivity and various other physical properties of the transition elements are related and unified.
| Item Type: | Article |
|---|---|
| Date Type: | Publication |
| Status: | Published |
| Schools: | Schools > Engineering |
| Subjects: | T Technology > TK Electrical engineering. Electronics Nuclear engineering |
| Uncontrolled Keywords: | superconductivity, elements, lattice instabilities, periodic table, transition metals |
| Publisher: | The Royal Society |
| ISSN: | 1364-503X |
| Last Modified: | 01 Nov 2022 11:09 |
| URI: | https://orca.cardiff.ac.uk/id/eprint/93991 |
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