Lawrence, S. C., Ward, Benjamin David  ORCID: https://orcid.org/0000-0003-1406-5940, Dubberley, S. R., Kozak, C. M. and Mountford, P.
2003.
Highly efficient ethylene polymerisation by scandium alkyls supported by neutral fac-kappa(3) coordinated N-3 donor ligands.
Chemical Communications
(23)
, pp. 2880-2881.
10.1039/B310867H
|
Abstract
Reaction of [M(CH2SiMe3)3(THF)2] (M = Sc or Y) with the neutral fac-κ3 N3 donor ligands (L) Me3[9]aneN3 or HC(Me2pz)3 gave the corresponding trialkyls [M(L)(CH2SiMe3)3]; activation of the scandium congeners with B(C6F5)3 in the presence of ethylene afforded highly active polymerisation catalysts (Me3[9]aneN3 = 1,4,7-trimethyltriazacyclononane).
| Item Type: | Article |
|---|---|
| Date Type: | Publication |
| Status: | Published |
| Schools: | Schools > Chemistry |
| Subjects: | Q Science > QD Chemistry |
| Publisher: | RSC Publishing |
| ISSN: | 1359-7345 |
| Last Modified: | 18 Oct 2022 12:24 |
| URI: | https://orca.cardiff.ac.uk/id/eprint/9712 |
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