Structural studies of Perfluoroaryldiselenadiazolyl Radicals: Insights into Dithiadiazolyl Chemistry

Melen, Rebecca ORCID: https://orcid.org/0000-0003-3142-2831, Less, Robert J., Pask, Christopher M. and Rawson, Jeremy M. 2016. Structural studies of Perfluoroaryldiselenadiazolyl Radicals: Insights into Dithiadiazolyl Chemistry. Inorganic Chemistry 55 (22) , pp. 11747-11759. 10.1021/acs.inorgchem.6b01771

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Abstract

Synopsis Diselenadiazolyls exhibit a stronger tendency to dimerize in the solid state than their corresponding dithiadiazolyl (DTDA) radicals, reflected in a range of dimerization modes for (p-XC6F4CNSeSeN)2, which contrast with those of the monomeric DTDA radicals, p-XC6F4CNSSN. The structure of (p-NCC6F4CNSeSeN)2 reflects a buildup of molecular strain in order to accommodate both dimerization and structure-directing CN···Se contacts, whereas the suppression of dimerization releases molecular strain yet retains structure-directing CN···S contacts for the corresponding DTDA radical.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry
Subjects:	Q Science > QD Chemistry
Publisher:	American Chemical Society
ISSN:	0020-1669
Funders:	EPSRC
Date of First Compliant Deposit:	17 January 2017
Date of Acceptance:	1 November 2016
Last Modified:	05 May 2023 12:52
URI:	https://orca.cardiff.ac.uk/id/eprint/97503

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