Nucleophile-selective selenocyclizations

Khokhar, Shaista Sheroze and Wirth, Thomas ORCID: https://orcid.org/0000-0002-8990-0667 2004. Nucleophile-selective selenocyclizations. European Journal of Organic Chemistry (22) , pp. 4567-4581. 10.1002/ejoc.200400526

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Abstract

Electrophilic cyclizations are one of the major strategies for cyclofunctionalizations of alkenes. Selective selenocyclizations can be performed by adjusting various factors in such reactions. The nature of the electrophile, the counterion, solvents, and external additives coordinating to the electrophilic species are used to control the course of such cyclizations with high degrees of efficiency. Our investigations have been extended towards stereoselective reactions using chiral selenium electrophiles.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry
Subjects:	Q Science > QD Chemistry
Uncontrolled Keywords:	Alkenes; Electrophiles; Heterocycles; Selenium; Stereoselective synthesis
Publisher:	Wiley-Blackwell
ISSN:	1434-193X
Last Modified:	18 Oct 2022 12:25
URI:	https://orca.cardiff.ac.uk/id/eprint/9767

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