Delocalized hypervalent silyl radical supported by amidinate and imino substituents

Zhang, Shu Hua, Carter, Emma ORCID: https://orcid.org/0000-0001-6691-2377, Xi, Hong-Wei, Li, Yongxin, Lim, Kok Hwa and So, Cheuk-Wai 2016. Delocalized hypervalent silyl radical supported by amidinate and imino substituents. Inorganic Chemistry 56 (2) , pp. 701-704. 10.1021/acs.inorgchem.6b02427

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Abstract

The reaction of the amidinato silylsilylene with a functionalized diaminochlorosilyl substituent [LSiSi(Cl){(NtBu)2C(H)Ph}] (1, L = PhC(NtBu)2) with ArN=C=NAr (Ar = 2,6-iPr2C6H3) in toluene afforded the delo-calized hypervalent silyl radical [LSi(-CNAr)2Si{(NtBu)2C(H)Ph}] (2). It possesses a hypervalent silyl radical, which delocalizes throughout the Si2C2 ring.

Item Type:	Article
Date Type:	Published Online
Status:	Published
Schools:	Schools > Chemistry
Subjects:	Q Science > QD Chemistry
Publisher:	American Chemical Society
ISSN:	0020-1669
Date of First Compliant Deposit:	27 January 2017
Date of Acceptance:	23 December 2016
Last Modified:	30 Nov 2024 21:00
URI:	https://orca.cardiff.ac.uk/id/eprint/97829

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