The effect of carboxylate position on the structure of a metal organic framework derived from cyclotriveratrylene

Martin, Adam D., Easun, Timothy ORCID: https://orcid.org/0000-0002-0713-2642, Argent, Stephen P., Lewis, William, Blake, Alexander J. and Schröder, Martin 2017. The effect of carboxylate position on the structure of a metal organic framework derived from cyclotriveratrylene. Crystengcomm 19 (4) , pp. 603-607. 10.1039/C6CE01965J

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Abstract

Two cyclotriveratrylene-based ligands H3L1 and H3L2 have been synthesised using microwave heating and used in the formation of 1 [Zn2(L1)(DMA)2(CH3COO)] and 2 [Zn6(L2)4(DMA)6(H2O)5] (DMA = N,N-dimethylacetamide). 1 displays an unusual trigonal paddlewheel node geometry, while Zn(II) paddlewheels are observed in 2. However, the stacking of CTV molecules in 1 is replaced by an uncommon molecular capsule structure in 2.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Schools > Chemistry
Subjects:	Q Science > QD Chemistry
Publisher:	Royal Society of Chemistry
ISSN:	1466-8033
Funders:	EPSRC, ERC and Royal Society
Date of First Compliant Deposit:	6 February 2017
Date of Acceptance:	1 October 2016
Last Modified:	05 May 2023 10:59
URI:	https://orca.cardiff.ac.uk/id/eprint/98094

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