Highly flexible phosphabenzenes: a missing coordination mode of 2,4,6-triaryl-λ3-phosphinines

Yue, Erlin, Petrov, Andrey, Frost, Daniel S., Dettling, Lea, Conrad, Lawrence, Wossidlo, Friedrich, Coles, Nathan T. ORCID: https://orcid.org/0000-0001-6190-9080, Weber, Manuela and Müller, Christian 2022. Highly flexible phosphabenzenes: a missing coordination mode of 2,4,6-triaryl-λ3-phosphinines. Chemical Communications 58 (42) , pp. 6184-6187. 10.1039/D2CC01817A

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Abstract

The reaction of 2,4,6-triaryl-λ3-phosphinine-Cr(CO)3-π-complexes with [Rh(COD)2]BF4 leads to unusual diamagnetic Rh0-dimers, which contain two phosphinine-π-complexes acting as a bridging 2e−-ligand towards the Rh2(CO)2 core. These compounds represent a missing coordination mode for the aromatic 6-membered phosphorus heterocycle.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Schools > Chemistry
Publisher:	Royal Society of Chemistry
ISSN:	1359-7345
Date of First Compliant Deposit:	3 December 2024
Date of Acceptance:	13 April 2022
Last Modified:	03 Dec 2024 14:16
URI:	https://orca.cardiff.ac.uk/id/eprint/173590

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