Xiao, Shanshan, Zhao, Mingjun, Li, Mingquan, Wan, Shanhong, Genc, Aziz, Huang, Lulu, Chen, Lei, Zhang, Yu, Ibáñez, Maria, Lim, Khak Ho, Hong, Min, Liu, Yu and Cabot, Andreu
2025.
Band and defect engineering in solution-processed nanocrystal building blocks to promote transport properties in nanomaterials: The case of thermoelectric Cu
3SbSe
4.
Nano Research
18
(1)
, 94907072.
10.26599/NR.2025.94907072
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Abstract
The development of cost-effective and high-performance thermoelectric (TE) materials faces significant challenges, particularly in improving the properties of promising copper-based TE materials such as Cu3SbSe4, which are limited by their poor electrical conductivity. This study presents a detailed comparative analysis of three strategies to promote the electrical transport properties of Cu3SbSe4 through Sn doping: conventional Sn atomic doping, surface treatment with SnSe molecular complexes, and blending with SnSe nanocrystals to form nanocomposites, all followed by annealing and hot pressing under identical conditions. Our results reveal that a surface treatment using SnSe molecular complexes significantly enhances TE performance over atomic doping and nanocomposite formation, achieving a power factor of 1.1 mW·m−1·K−2 and a maximum dimensionless figure of merit zT value of 0.80 at 640 K, representing an excellent performance among Cu3SbSe4-based materials produced via solution-processing methods. This work highlights the effectiveness of surface engineering in optimizing the transport properties of nanostructured materials, demonstrating the versatility and cost-efficiency of solution-based technologies in the development of advanced nanostructured materials for application in the field of TE among others.
| Item Type: | Article |
|---|---|
| Date Type: | Published Online |
| Status: | Published |
| Schools: | Research Institutes & Centres > Cardiff Catalysis Institute (CCI) Schools > Chemistry |
| Publisher: | Springer |
| ISSN: | 1998-0124 |
| Date of First Compliant Deposit: | 2 April 2025 |
| Date of Acceptance: | 11 October 2024 |
| Last Modified: | 04 Apr 2025 11:49 |
| URI: | https://orca.cardiff.ac.uk/id/eprint/177363 |
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