Garcia Canadas, Jorge, Powell, Anthony V., Kaltzoglou, Andreas, Vaqueiro, Paz and Min, Gao  ORCID: https://orcid.org/0000-0001-9591-5825
      2013.
      
      Fabrication and evaluation of a skutterudite-based thermoelectric module for high-temperature applications.
      Journal of Electronic Materials
      42
      
        (7)
      
      , pp. 1369-1374.
      
      10.1007/s11664-012-2241-0
    
  
  
       
       
     
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Abstract
We report a straightforward methodology for the fabrication of high-temperature thermoelectric (TE) modules using commercially available solder alloys and metal barriers. This methodology employs standard and accessible facilities that are simple to implement in any laboratory. A TE module formed by nine n-type Yb x Co4Sb12 and p-type Ce x Fe3CoSb12 state-of-the-art skutterudite material couples was fabricated. The physical properties of the synthesized skutterudites were determined, and the module power output, internal resistance, and thermocycling stability were evaluated in air. At a temperature difference of 365 K, the module provides more than 1.5 W cm−3 volume power density. However, thermocycling showed an increase of the internal module resistance and degradation in performance with the number of cycles when the device is operated at a hot-side temperature higher than 573 K. This may be attributed to oxidation of the skutterudite thermoelements.
| Item Type: | Article | 
|---|---|
| Date Type: | Publication | 
| Status: | Published | 
| Schools: | Schools > Engineering | 
| Subjects: | T Technology > TK Electrical engineering. Electronics Nuclear engineering | 
| Uncontrolled Keywords: | Thermoelectric generator; skutterudites; manufacturing; electrical contact resistivity; power output; device fabrication | 
| Publisher: | Springer | 
| ISSN: | 0361-5235 | 
| Last Modified: | 24 Oct 2022 10:43 | 
| URI: | https://orca.cardiff.ac.uk/id/eprint/45594 | 
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