Matthai, Clarence Cherian and March, N. H. 2007. On the pressure dependence of the melting temperature and the monovacancy formation energy in transition metals. Philosophical Magazine Letters 87 (7) , pp. 475-482. 10.1080/09500830701320307 |
Official URL: http://dx.doi.org/10.1080/09500830701320307
Abstract
We demonstrate that the wide range of magnitudes observed for the slopes of the melting curves at zero pressure for some transition metals with incomplete d-shells are consistent with their elastic moduli data. The near-zero slopes observed for W and Mo are not anomalous as has been suggested recently. We propose an empirical non-linear relationship between the slope and the compressibility. By examining a model for the vacancy formation energy in these metals, we show that the slopes can also be related to the slopes of the melting curves.
Item Type: | Article |
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Date Type: | Publication |
Status: | Published |
Schools: | Physics and Astronomy |
Subjects: | Q Science > QC Physics |
Publisher: | Taylor & Francis Online |
ISSN: | 0950-0839 |
Last Modified: | 04 Jun 2017 05:03 |
URI: | https://orca.cardiff.ac.uk/id/eprint/47779 |
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