Transport and thermodynamic properties in low melting point ionic liquids related ton-alkyl chain length

Balaban, A. T., Klein, D. J., March, N. H. and Matthai, Clarence Cherian 2005. Transport and thermodynamic properties in low melting point ionic liquids related ton-alkyl chain length. Physics and Chemistry of Liquids 43 (4) , pp. 403-407. 10.1080/00319100500165976

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Abstract

Room-temperature ionic liquids (RTIL) are offering ‘green’ alternatives to organic solvents in industrial processes. Therefore, we propose here, with n-alkyl chain length as the focus, some inter-relationships involving transport as well as thermodynamic properties. Experimental work is suggested to examine whether (a) extended defect models of melting are useful for RTIL and (b) the product of surface tension and isothermal compressibility, which has the dimensions of length, varies systematically with the choice of anions as well as with the number of carbon atoms in the n-alkyl chain.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Physics and Astronomy
Subjects:	Q Science > QC Physics
Publisher:	Taylor & Francis
ISSN:	0031-9104
Last Modified:	04 Jun 2017 05:03
URI:	https://orca.cardiff.ac.uk/id/eprint/47782

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